Improving the Quality of Bio-Oil Produced from Rice Husk Pyrolysis by Extraction of its Phenolic Compounds


Dewi Selvia Fardhyanti, - (2019) Improving the Quality of Bio-Oil Produced from Rice Husk Pyrolysis by Extraction of its Phenolic Compounds. Jurnal Bahan Alam Terbarukan, 8 (2). pp. 90-100. ISSN 2407-2370

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Abstract

Rice husk is an agricultural waste which contains 50% cellulose, 25%-30% lignin and 15%- 20% silica. It can be used as raw material of bio-oil. Bio-oil is liquid which produced by pyrolysis process. Bio-oil can be produced from the rice husk at 773 and 873 K. The main component of Bio-oil from rice husk pyrolysis at 773 and 873 K is phenolic compounds about 47.98% and 62.65%, respectively. It causes corrosive, low heating value, high acidity, high viscosity and unstable that causing an engine damage. The presence of phenolic compound decreases the quality of bio-oil. Therefore, it needs a process such as liquid- liquid extraction to reduce the phenolic compound using 80% methanol and 80% chloroform as a solvent. The extract and raffinate phase were analyzed using UV-Vis spectrophotometer. The aim of this research determine the effect of temperature pyrolysis for the characterization of bio-oil, the stirring speed and the temperature of the extraction for the distribution coefficient and the yield of phenolic compound. The results showed that the characterization of bio-oil produced from rice husk pyrolysis at 773 and 873 K are densities 1,040 and 1,042 Kg/m3; viscosities 9.3488 and 9.5007 cSt; acid numbers 46.75 and 52.45 mg KOH/g; pH 2.5 and 3; flash points 426 and 423 K and heating values 3.229 and 3.339 MJ/kg, respectively. The highest distribution coefficient and yield were obtained at 323 K and a stirring speed of 250 rpm. The distribution coefficient of bio-oil produced by pyrolysis at 773 and 873 K is 1.504, and 1.528, respectively. The yields of bio-oil produced by pyrolysis at 773 and 873 K are 58.885%, and 48.429%, respectively.

Item Type: Article
Subjects: Q Science > Q Science (General)
T Technology > TP Chemical technology
Fakultas: Fakultas Teknik > Teknik Kimia, S1
Depositing User: dina nurcahyani perpus
Date Deposited: 23 Mar 2021 04:43
Last Modified: 10 Jan 2022 03:26
URI: http://lib.unnes.ac.id/id/eprint/43465

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